Tethered Axial Coordination as a Control Element on Dirhodium Paddlewheel Complexes Professor Ampofo Darko from The University of Tennessee, Knoxville will present a seminar, Tethered Axial Coordination as a Control Element on Dirhodium Paddlewheel Complexes Abstract: Dirhodium(II,II) paddlewheel (RhII) complexes can mediate a number of transformations through the catalytic transfer of carbenes from diazo precursors. The reactivity and selectivity of these reactions are modulated partly by the modification of bridging ligands surrounding the metal center, but the axial sites of [...]